ETS Major Field Test Chemistry 2025 – 400 Free Practice Questions to Pass the Exam

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What is the characteristic structure of benzene?

Two carbon atoms connected by a single bond

A straight chain of carbon atoms

A hexagonal ring with alternating double bonds

Benzene is recognized for its unique and stable structure, which consists of a hexagonal ring made up of six carbon atoms. Each carbon atom in benzene is bonded to one hydrogen atom, resulting in a molecular formula of C6H6. The defining feature of benzene is the alternating double bonds that create a system of resonance. This resonance stabilizes the molecule, leading to a situation where the bond lengths between carbon atoms are equal and intermediate between single and double bond lengths.

This characteristic hexagonal arrangement contributes to benzene’s aromatic properties, allowing it to participate in substitution reactions rather than addition reactions that typical alkenes undergo. This stability due to resonance is a fundamental aspect of benzene, distinguishing it from other structures.

Other options depict incorrect forms: connections through single bonds or tetrahedral geometry do not accurately represent the benzene structure, while a straight chain (as in aliphatic hydrocarbons) lacks the ring formation that is essential to benzene's identity. Understanding the unique hexagonal ring structure of benzene, with its resonance stability, is crucial for recognizing its properties and reactivity in organic chemistry.

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A tetrahedral structure

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